{N,N′-Bis[2-(diphenylphosphanyl)ethan-1-ylidene]ethylenediamine}bromido(p-toluenesulfonylmethyl isocyanide)iron(II) tetraphenylborate
نویسندگان
چکیده
In the title compound, [FeBr(C9H9NO2S)(C30H30N2P2)][B(C6H5)4], the Fe(II) ion is in a distorted octa-hedral CBrN2P2 coordination geometry with a P-Fe-P angle of 109.95 (3)°. The relative orientation of the p-toluene-sulfonyl-methyl isocyanide ligand is defined by the C-S-C-N torsion angle of 67.1 (2)°. In the crystal, pairs of weak C-H⋯O hydrogen bonds connect the cations into inversion dimers, forming R 2 (2)(8) rings.
منابع مشابه
(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN 4)bis(nitrato-κO)nickel(II) monohydrate
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